منابع مشابه
Ordering of Interfacial Water Molecules at the Charged Air/Water Interface Observed by Vibrational Sum Frequency Generation
The molecular structure and orientation of interfacial water molecules at the air/water interface in the presence of soluble cationic and anionic surfactants has been characterized. We have employed vibrational sum frequency generation (VSFG) to probe the orientation of interfacial water molecules as a function of both bulk surfactant concentration and solution ion strength. The observed orderi...
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Accumulation at the air-water interface of four bacterial strains with different hydrophobicities was studied. To exclude system influences, both a static batch system and a dynamic system involving rising bubbles were used. All bacteria accumulated at the air-water interface in both systems. Generally, attachment to the air-water interface increased with bacterial surface hydrophobicity. Accum...
متن کاملOrganic ions at the air/water interface
Direct spectroscopic evidence of the presence of organic phenolate ions at the air/aqueous interface has been established using the nonlinear spectroscopic technique of vibrational sum frequency generation (SFG). By probing the phenol C–OH and the phenolate C–O vibrational stretches, which occur in the range of 1200–1300 cm and are distinguishable, we have succeeded in determining the identitie...
متن کاملHydrated electrons at the water/air interface.
The dynamics of hydrated electrons at the water/air interface are investigated using time-resolved second-harmonic generation spectroscopy. Initial solvation occurs in approximately 1 ps, and the electron remains at the interface for >750 ps. The location of the electron relative to the dividing surface is investigated using surfactants, which show that the electron is hydrated in the interfaci...
متن کاملBrønsted basicity of the air-water interface.
Differences in the extent of protonation of functional groups lying on either side of water-hydrophobe interfaces are deemed essential to enzymatic catalysis, molecular recognition, bioenergetic transduction, and atmospheric aerosol-gas exchanges. The sign and range of such differences, however, remain conjectural. Herein we report experiments showing that gaseous carboxylic acids RCOOH(g) begi...
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ژورنال
عنوان ژورنال: Current Opinion in Colloid & Interface Science
سال: 2018
ISSN: 1359-0294
DOI: 10.1016/j.cocis.2018.07.002